Anti-Stokes photoluminescence from <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>CsPbBr</mml:mi><mml:mn>3</mml:mn></mml:msub></mml:math> nanostructures embedded in a <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>Cs</mml:mi><mml:mn>4</mml:mn></mml:msub><mml:msub><mml:mi>PbBr</mml:mi><mml:mn>6</mml:mn></mml:msub></mml:mrow></mml:math> crystal
نویسندگان
چکیده
Lead halide perovskites possess high photoluminescence (PL) efficiency and strong electron-phonon interactions, therefore optical cooling using up-conversion PL has been expected. We investigate anti-Stokes from green-luminescent ${\mathrm{Cs}}_{4}{\mathrm{PbBr}}_{6}$, whose origin is attributable to ${\mathrm{CsPbBr}}_{3}$ nanostructures embedded in a ${\mathrm{Cs}}_{4}{\mathrm{PbBr}}_{6}$ crystal. Because of the transparency, low refractive index, stability green displays external quantum without photodegradation. Time-resolved spectroscopy reveals excitonic behaviors recombination process. The shape spectrum almost independent excitation photon energy, which means that spectral width determined by homogeneous broadening. demonstrate phonon-assisted process dominates Urbach tail absorption at room temperature. Anti-Stokes observed down 70 K. determine temperature dependence energy estimate strength coupling. Our spectroscopic data show have potentially useful features for cooling.
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ژورنال
عنوان ژورنال: Physical Review Materials
سال: 2022
ISSN: ['2476-0455', '2475-9953']
DOI: https://doi.org/10.1103/physrevmaterials.6.l043001